The titles of the diploma and Ph.D. theses that have been completed to date at the
institute E15 are available online, some with summaries. In some cases the
complete thesis is available. The theses are ordered according to the
primary measurement technique:
Study of the Spinglass Behaviour of beta-Mn(Sn) Solid Solutions
While the alpha and beta modifications of manganese order antiferromagnetically,
beta manganese, stable between 727 and 1100°C, shows paramagnetic behaviour
down to very low temperatures. NMR and Mössbauer investigations, however,
showed that only small impurities of other metals lead to the onset of magnetism.
A possible explanation for this behaviour is that the complex structure of
beta manganese is connected with a frustration of the magnetic interaction which
is removed by the impurity atoms. This then leads to a spinglass-like freezing
of the magnetic manganese moments. This notion is in line with the fact that
neutron diffraction experiments failed to detect any long-range magnetic order
in the diluted alloys.
Within this thesis, diluted beta-Mn(Sn) alloys are to be studied
systematically by means of Mössbauer spectroscopy
on the isotope 119Sn. In addition, magnetization and susceptibility
measurements are planned in collaboration with the University College London,
using a SQUID magnetometer available there (travel funds for conducting
these measurements in London are available). Additionally the thesis includes
the preparation of the alloys with an arc furnace and the thermal treatment
of the sample to obtain the beta modification of manganese, which is
metastable at ambient temperature.
Supervisor: Prof. Dr. F. E. Wagner (see phone listing)
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Study of the Magnetic Properties of Systems with Strongly Correlated Electrons
by Means of Muon Spin Relaxation
Continuing the work of a recently completed diploma thesis, it is planned to perform
and evaluate further µSR measurements
on various samples of the system CeNiCu1-xSnx.
Due to its special properties among the "systems of strongly correlated electrons",
the intermetallic Ce compound CeNiSn has aroused special interest during recent
years (CeNiSn is often called a "Kondo semiconductor"). By doping with Cu, the lattice
parameter and the electronic structure of CeNiSn can be changed specifically. In the
above mentioned diploma thesis, spinglass behaviour could be observed in a sample
doped with 10% copper, in contrast to pure CeNiSn. At the lowest studied temperatures
in the mK regime (measured by means of a He3/He4 dilution
refrigerator) a perturbed magnetic order prevails. Further µSR experiments
over a wider concentration range are necessary to classify the type of the magnetic
order. Recently, two new samples with Cu concentrations of 5 and 20 %, respectively,
have become available.
The measurements are connected with several short trips (about 2 weeks) to the
Rutherford Appleton Laboratory (RAL) in England (near Oxford). There the spallation
neutron source ISIS also offers several µSR measurement facilities.
The project is a cooperation with several international research groups from
the Hiroshima University (Japan), the Virginia State University (USA), the
University of Southhampton (UK), and the University of Uppsala (Sweden).
Supervisor: Dr. A. Kratzer (see phone listing)
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